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Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles
(Beilstein Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2015-04-28)
Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO4 or, alternatively,
under high-pressure conditions (5 kbar) at room temperature yielding thiopyran ...