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Metal-Dependent Cytotoxic and Kinesin Spindle Protein Inhibitory Activity of Ru, Os, Rh, and Ir Half-Sandwich Complexes of IspinesibDerived Ligands
(American Chemical Society, 2020)
Ispinesib is a potent inhibitor of kinesin spindle protein (KSP), which has been identified as a promising target for antimitotic anticancer drugs. Herein, we report the synthesis of half-sandwich complexes of Ru, Os, Rh, ...
A new class of pyrenyl solid-state emitters: 1-pyrenyl ynones. Synthesis via the Friedel–Crafts route, molecular and electronic structure and photophysical properties
(The Royal Society of Chemistry, 2014-06-15)
Friedel–Crafts acylation of pyrene with alkynoic acids in the presence of trifluoroacetic anhydride and triflic acid constitutes a direct and efficient route to 1-pyrenyl ynones. These compounds in chloroform solution emit ...
Efficient synthesis of pyrene-1-carbothioamides and carboxamides. Tunable solid-state fluorescence of pyrene-1-carboxamides
(The Royal Society of Chemistry, 2014-10-23)
Pyrene reacts with potassium thiocyanate and organic isothiocyanates in the presence of
trifluoromethanesulfonic acid to afford primary and secondary pyrene-1-carbothioamides in high yields.
These compounds were efficiently ...