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THE REACTION OF TETRAMETHYLSILANE WITH BORON TRIBROMIDE
(Walter de Gruyter (Previously published by Freund Publishing House Ltd.), 2001-12-01)
The reaction of tetramethylsilane with boron tribromide in deuterochloroform in ambient temperature or at 40°C led to bromotrimethylsilane (3) and to dibromomethylborane (4). Identity of products was confirmed by NMR ...
Synthesis, Chemistry and Applications of 5-Hydroxymethyl-furfural And Its Derivatives
HMF is a good starting material for the synthesis of precursors of various pharmaceuticals, thermo-resistant polymers and complex macrocycles. Among these precursors, one can find 2,5- furandicarbaldehyde and ...
Synthesis and structure determination of stereoisomeric 2,2’-dibenzoyl-3,3’,4,4’-tetramethyl-1,1’-diphosphaferrocenes
(ARKAT USA, 2007)
Reaction of 3,3’,4,4’-tetramethyl-1,1’-diphosphaferrocene 1 with an excess of benzoyl chloride and AlCl3 afforded a ~1:1 mixture of meso- and rac-2,2’-dibenzoyl-3,3’,4,4’-tetramethyl-1,1’- diphosphaferrocenes 2, which ...