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dc.contributor.authorTyczyńska, Magdalena
dc.contributor.authorJóźwiak, Małgorzata
dc.description.abstractThe density of 15-crown-5 ether (15C5) solutions in the mixtures of N,N-dimethylformamide (DMF) and water (H_2O) was measured within the temperature range 293.15–308.15 K using an Anton Paar oscillatory U-tube densimeter. The results were used to calculate the apparent molar volumes (V Φ ) of 15C5 in the mixtures of DMF + H_2O over the whole concentration range. Using the apparent molar volumes and Redlich and Mayer equation, the standard partial molar volumes of 15-crown-5 were calculated at infinite dilution (V_m^o). The limiting apparent molar expansibilities (α) were also calculated. The data are discussed from the point of view of the effect of concentration changes on interactions in solution.pl_PL
dc.description.sponsorshipThis study was supported by ZPORR, Project: Post-graduate students—Regional Investment in Young Scientists D-RIM II edition co-financed by the European Union from the European Social Fund within the Operational Program Human Capital (Human—best investment), which is gratefully acknowledged. The authors would like to thank Prof. Adam Bald for discussion and Prof. W. Earle Waghorne for useful suggestions.pl_PL
dc.publisherSpringer USpl_PL
dc.relation.ispartofseriesJournal of Solution Chemistry;2
dc.rightsUznanie autorstwa 3.0 Polska*
dc.subjectN,N-Dimethylformamide–water mixturepl_PL
dc.subjectPartial molar volumepl_PL
dc.subjectHydrophobic hydrationpl_PL
dc.titlePartial Molar Volumes of 15-Crown-5 Ether in Mixtures of N,N-Dimethylformamide with Waterpl_PL
dc.contributor.authorAffiliationUniversity of Lodz, Department of Physical Chemistrypl_PL
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Uznanie autorstwa 3.0 Polska
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