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Author
Alexey, V. Ivanov (1)
Baranovskii, Viktor I. (1)Mereshchenko, Andrey S. (1)Mloston, Grzegorz (1)Nikolaev, Valerij A. (1)Rodina, Ludmila L. (1)Subject1,3-dipolar cycloaddition (1)1,3-oxathioles (1)
diazocarbonyl compounds (1)
thiiranes (1)thiocarbonyl ylides (1)thioketones (1)... View MoreDate Issued2015 (1)Has File(s)Yes (1)

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On the strong difference in reactivity of acyclic and cyclic diazodiketones with thioketones: experimental results and quantum-chemical interpretation 

Mereshchenko, Andrey S.; Alexey, V. Ivanov; Baranovskii, Viktor I.; Rodina, Ludmila L.; Nikolaev, Valerij A.; Mloston, Grzegorz (Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2015-04-20)
The 1,3-dipolar cycloaddition of acyclic 2-diazo-1,3-dicarbonyl compounds (DDC) and thioketones preferably occurs with Z,Econformers and leads to the formation of transient thiocarbonyl ylides in two stages. The ...

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