Wydział Chemii | Faculty of Chemistry: Recent submissions
Now showing items 141-160 of 195
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Temperature-dependent polymorphism of N-(4-fluorophenyl)-1,5-dimethyl-1H-imidazole-4-carboxamide 3-oxide: experimental and theoretical studies on intermolecular interactions in the crystal state
(Springer US, 2014)X-ray analysis of N-(4-fluorophenyl)-1,5-dimethyl-1H-imidazole-4-carboxamide 3-oxide reveals the temperature-dependent polymorphism associated with the crystallographic symmetry conversion. The observed crystal structure ... -
Atypical McMurry Cross-Coupling Reactions Leading to a New Series of Potent Antiproliferative Compounds Bearing the Key [Ferrocenyl-Ene-Phenol] Motif
(MDPI, 2014)In the course of the preparation of a series of ferrocenyl derivatives of diethylstilbestrol (DES), in which one of the 4-hydroxyphenyl moieties was replaced by a ferrocenyl group, the McMurry reaction of chloropropionylferrocene ... -
Dielectric Properties and Characterisation of Titanium Dioxide Obtained by Different Chemistry Methods
(Hindawi Publishing Corporation, 2014)We made comparison of titanium dioxide powders obtained from three syntheses including sol-gel and precipitation methods as well as using layered (tetramethyl)ammonium titanate as a source of TiO2. The obtained precursors ... -
Tannic Acid Modified Silver Nanoparticles Show Antiviral Activity in Herpes Simplex Virus Type 2 Infection
(PLOS, 2014)The interaction between silver nanoparticles and herpesviruses is attracting great interest due to their antiviral activity and possibility to use as microbicides for oral and anogenital herpes. In this work, we demonstrate ... -
The differences in thermal profiles between normal and leukemic cells exposed to anticancer drug evaluated by differential scanning calorimetry
(Springer Netherlands, 2014)Chronic lymphocytic leukemia (CLL) is a heterogenous disease with an imbalance between apoptosis and cell proliferation. Therefore, the main goal in CLL therapy is to induce apoptosis and effectively support this process ... -
Partial Molar Volumes of 15-Crown-5 Ether in Mixtures of N,N-Dimethylformamide with Water
Tyczyńska, Magdalena
; (Springer US, 2014)
The density of 15-crown-5 ether (15C5) solutions in the mixtures of N,N-dimethylformamide (DMF) and water (H_2O) was measured within the temperature range 293.15–308.15 K using an Anton Paar oscillatory U-tube densimeter. ... -
Chromatograficzne badania tiazolidynowych i tiazynowych pochodnych endogennych aldehydów
(2015)Celem pracy doktorskiej było zbadanie możliwości tworzenia się adduktów pomiędzy homocysteiną i cysteiną a aldehydami (mrówkowym, octowym, fosforanem 5’-pirydoksalu) w warunkach fizjologicznych zarówno in vitro jak i in ... -
Synteza i kontrolowana depozycja nanocząstek złota techniką elektrorozpylania
(2015)The main dissertation subject is the study on new synthesis method of highly monodisperse gold nanoparticles in organic media and elaboration of nanoparticles deposition technique onto different substrates including ... -
Effect of base–acid properties of the mixtures of water with methanol on the solution enthalpy of selected cyclic ethers in this mixture at 298.15 K
(Akadémiai Kiadó, 2015-03-27)The enthalpies of solution of cyclic ethers: 1,4- dioxane, 12-crown-4 and 18-crown-6 in the mixture of water and methanol have been measured within the whole mole fraction range at T = 298.15 K. Based on the obtained data, ... -
The influence of the chain length and the functional group steric accessibility of thiols on the phase transfer efficiency of gold nanoparticles from water to toluene
(West Pomeranian University of Technology, Szczecin, POLAND, Publishing House, 2014)This paper describes the influence of the chain length and the functional group steric accessibility of thiols modifiers on the phase transfer process efficiency of water synthesized gold nanoparticles (AuNPs) to toluene. ... -
The substituent effect on benzene dications
(RSC Publishing, 2014-01-03)It was recently postulated that the benzene ring and its 4n + 2 p-electron analogues are resistant to the substituent effect due to the fact that such systems tend to retain their delocalized character. Therefore, the 4n ... -
Effects of serum proteins on corrosion behavior of ISO 5832–9 alloy modified by titania coatings
(Springer Berlin Heidelberg, 2014-09-26)Stainless steel ISO 5832–9 type is often used to perform implants which operate in protein-containing physiological environments. The interaction between proteins and surface of the implant may affect its corrosive ... -
Structural analysis and corrosion studies on an ISO 5832-9 biomedical alloy with TiO2 sol–gel layers
(Springer, 2013-11-23)The aim of this study was to demonstrate the relationship between the structural and corrosion properties of an ISO 5832-9 biomedical alloy modified with titanium dioxide (TiO2) layers. These layers were obtained via ... -
Synteza fosfonowych pochodnych izoindolinonu
(2015)Przedmiotem niniejszej rozprawy doktorskiej było opracowanie metod syntezy fosfonowych pochodnych izoindolinonu B, w których ugrupowanie fosfonowe połączone jest z pierścieniem heterocyklicznym w pozycji 3 poprzez jeden, ... -
Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles
(Beilstein Beilstein-Institut zur Förderung der Chemischen Wissenschaften, 2015-04-28)Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO4 or, alternatively, under high-pressure conditions (5 kbar) at room temperature yielding thiopyran ... -
On the strong difference in reactivity of acyclic and cyclic diazodiketones with thioketones: experimental results and quantum-chemical interpretation
(Beilstein Institute for the Advancement of Chemical Sciences, 2015-04-20)The 1,3-dipolar cycloaddition of acyclic 2-diazo-1,3-dicarbonyl compounds (DDC) and thioketones preferably occurs with Z,Econformers and leads to the formation of transient thiocarbonyl ylides in two stages. The ... -
Densymetryczne i wiskozymetryczne badania hydrofobowej hydratacji wybranych związków organicznych w mieszaninach N,N-dimetyloformamidu z wodą
Tyczyńska, Magdalena (2015)
W niniejszej pracy doktorskiej przedstawiono rezultaty badań densymetrycznych i wiskozymetrycznych substancji rozpuszczonej (mocznik (U), tetrametylomocznik (TMU), 1,4-dioksan, eter 15-korona-5 (15C5) i eter 18-korona-6 ... -
Elektrody nowej generacji jako narzędzie w woltamperometrycznym oznaczaniu związków biologicznie czynnych
(2015)Głównym celem prowadzonych badań było zastosowanie elektrod stałych nowej generacji, tj. elektrody srebrnej z odnawialnym filmem amalgamatu srebra (Hg(Ag)FE) oraz elektrody diamentowej domieszkowanej borem (BDDE) do badania ... -
The Influence of Protonation on the Electroreduction of Bi (III) Ions in Chlorates (VII) Solutions of Different Water Activity
(Springer, 2015-02-24)We examined the electroreduction of Bi (III) ions in chlorate (VII) solutions under varied protonation conditions of the depolariser using voltammetric and impedance methods. The results of the kinetic parameter correlation ...