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Versatile Phase Transfer Method for the Efficient Surface Functionalization of Gold Nanoparticles: Towards Controlled Nanoparticle Dispersion in a Polymer Matrix

dc.contributor.authorRanoszek-Soliwoda, Katarzyna
dc.contributor.authorGirleanu, Maria
dc.contributor.authorTkacz-Szczesna, Beata
dc.contributor.authorRosowski, Marcin
dc.contributor.authorCelichowski, Grzegorz
dc.contributor.authorBrinkmann, Martin
dc.contributor.authorErsen, Ovidiu
dc.contributor.authorGrobelny, Jaroslaw
dc.date.accessioned2018-06-29T06:34:03Z
dc.date.available2018-06-29T06:34:03Z
dc.date.issued2016
dc.identifier.citationKatarzyna Ranoszek-Soliwoda, Maria Girleanu, Beata Tkacz-Szczęsna, et al., “Versatile Phase Transfer Method for the Efficient Surface Functionalization of Gold Nanoparticles: Towards Controlled Nanoparticle Dispersion in a Polymer Matrix,” Journal of Nanomaterials, vol. 2016, Article ID 9058323, 10 pages, 2016. https://doi.org/10.1155/2016/9058323.pl_PL
dc.identifier.issn1687-4110
dc.identifier.otherID 9058323
dc.identifier.urihttp://hdl.handle.net/11089/25214
dc.description.abstractIn electronic devices based on hybrid materials such as nonvolatile memory elements (NVMEs), it is essential to control precisely the dispersion of metallic nanoparticles (NPs) in an insulating polymer matrix such as polystyrene in order to control the functionality of the device. In this work the incorporation of AuNPs in polystyrene films is controlled by tuning the surface functionalization of the metallic nanoparticles via ligand exchange. Two ligands with different structures were used for functionalization: 1-decanethiol and thiol-terminated polystyrene. This paper presents a versatile method for the modification of gold nanoparticles (AuNPs) with thiol-terminated polystyrene ligands via phase transfer process. An organic colloid of AuNPs (5±1 nm diameter) is obtained by the phase transfer process (from water to toluene) that allows exchanging the ligand adsorbed on AuNPs surface (hydrophilic citrate/tannic acid to hydrophobic thiols). The stability, size distribution, and precise location of modified AuNPs in the polymer matrix are obtained from UV-Vis spectroscopy, dynamic light scattering (DLS), and electron tomography. TEM tomographic 3D imaging demonstrates that the modification of AuNPs with thiol-terminated polystyrene results in homogeneous particle distribution in the polystyrene matrix compared to 1-decanethiol modified AuNPs for which a vertical phase separation with a homogeneous layer of AuNPs located at the bottom of the polymer matrix was observed.pl_PL
dc.description.sponsorshipThis work was supported by FP7-NMP-2010-SMALL-4 Program (“Hybrid Organic/Inorganic Memory Elements for Integration of Electronic and Photonic Circuitry,” HYMEC), Project no. 263073. Eric Gonthier is acknowledged for technical support in the preparation of hybrid thin films. Scientific work was supported by the Polish Ministry of Science and Higher Education Funds for Science in 2011–2014 allocated for the cofunded international project.pl_PL
dc.language.isoenpl_PL
dc.publisherHindawi Publishing Corporationpl_PL
dc.relation.ispartofseriesJournal of Nanomaterials;2016
dc.rightsUznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/pl/*
dc.subjecttechnologypl_PL
dc.titleVersatile Phase Transfer Method for the Efficient Surface Functionalization of Gold Nanoparticles: Towards Controlled Nanoparticle Dispersion in a Polymer Matrixpl_PL
dc.typeArticlepl_PL
dc.rights.holderCopyright © 2016 Katarzyna Ranoszek-Soliwoda et al.pl_PL
dc.page.number1-10pl_PL
dc.contributor.authorAffiliationDepartment of Materials Technology and Chemistry, Faculty of Chemistry, University of Lodz, Pomorska 163, 90-236 Lodz, Polandpl_PL
dc.contributor.authorAffiliation2 Institut Charles Sadron, UPR-22 CNRS, 23 rue du Loess, BP 84047, 67034 Strasbourg Cedex 2, France; Institut de Physique et Chimie des Materiaux de Strasbourg, UMR 7504 CNRS-UdS, 23 rue du Loess BP 43, ´ 67034 Strasbourg Cedex 2, Francepl_PL
dc.contributor.authorAffiliationDepartment of Materials Technology and Chemistry, Faculty of Chemistry, University of Lodz, Pomorska 163, 90-236 Lodz, Polandpl_PL
dc.contributor.authorAffiliationDepartment of Materials Technology and Chemistry, Faculty of Chemistry, University of Lodz, Pomorska 163, 90-236 Lodz, Polandpl_PL
dc.contributor.authorAffiliationDepartment of Materials Technology and Chemistry, Faculty of Chemistry, University of Lodz, Pomorska 163, 90-236 Lodz, Polandpl_PL
dc.contributor.authorAffiliationInstitut Charles Sadron, UPR-22 CNRS, 23 rue du Loess, BP 84047, 67034 Strasbourg Cedex 2, Francepl_PL
dc.contributor.authorAffiliationInstitut de Physique et Chimie des Matériaux de Strasbourg, UMR 7504 CNRS-UdS, 23 rue du Loess BP 43, 67034 Strasbourg Cedex 2, Francepl_PL
dc.contributor.authorAffiliationDepartment of Materials Technology and Chemistry, Faculty of Chemistry, University of Lodz, Pomorska 163, 90-236 Lodz, Polandpl_PL
dc.identifier.eissn1687-4129
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dc.contributor.authorEmailjgrobel@uni.lodz.plpl_PL
dc.identifier.doi10.1155/2016/9058323


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Uznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska
Except where otherwise noted, this item's license is described as Uznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska