dc.contributor.author | Kowalski, Konrad | |
dc.contributor.author | Karpowicz, Rafał | |
dc.contributor.author | Mloston, Grzegorz | |
dc.contributor.author | Miesel, Dominique | |
dc.contributor.author | Hildebrandt, Alexander | |
dc.contributor.author | Lang, Heinrich | |
dc.contributor.author | Czerwieniec, Rafał | |
dc.contributor.author | Therrien, Bruno | |
dc.date.accessioned | 2015-08-28T12:31:45Z | |
dc.date.available | 2015-08-28T12:31:45Z | |
dc.date.issued | 2015-02-20 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://hdl.handle.net/11089/11589 | |
dc.description.abstract | Three novel diferrocenyl complexes were prepared and characterised. 2,2-Diferrocenyl-4,5-dimethyl-
3,6-dihydro-2H-thiopyran (1, sulphide) was accessible by the hetero-Diels–Alder reaction of diferrocenyl
thioketone with 2,3-dimethyl-1,3-butadiene. Stepwise oxidation of 1 gave the respective oxides 2,2-
diferrocenyl-4,5-dimethyl-3,6-dihydro-2H-thiopyran-1-oxide (2, sulfoxide) and 2,2-diferrocenyl-4,5-
dimethyl-3,6-dihydro-2H-thiopyran-1,1-dioxide (3, sulfone), respectively. The molecular structures of 1
and 3 in the solid state were determined by single crystal X-ray crystallography. The oxidation of sulphide
1 to sulfone 3, plays only a minor role on the overall structure of the two compounds. Electrochemical
(cyclic voltammetry (= CV), square wave voltammetry (= SWV)) and spectroelectrochemical (in situ
UV-Vis/NIR spectroscopy) studies were carried out. The CV and SWV measurements showed that an
increase of the sulphur atom oxidation from −2 in 1 to +2 in 3 causes an anodic shift of the ferrocenylbased
oxidation potentials of about 100 mV. The electrochemical oxidation of 1–3 generates mixedvalent
cations 1+–3+. These monooxidised species display low-energy electronic absorption bands
between 1000 and 3000 nm assigned to IVCT (= Inter-Valence Charge Transfer) electronic transitions.
Accordingly, the mixed-valent cations 1+–3+ are classified as weakly coupled class II systems according
to Robin and Day. | pl_PL |
dc.description.sponsorship | Authors (K. K. and G. M.) thank the National Science Centre
(Poland) for financial support (Project Maestro-3; Dec-2012/06/
A/ST5/00219) and R. C. thanks the German Federal Ministry of
Education and Research (BMBF) for support. The support
from the German Academic Exchange Service (DAAD) in the
framework of the exchange program “Ostpartnerschaften” is
highly appreciated. | pl_PL |
dc.language.iso | en | pl_PL |
dc.publisher | Royal Society of Chemistry | pl_PL |
dc.relation.ispartofseries | Dalton Transactions;2015 | |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.title | Synthesis and (spectro)electrochemistry of mixedvalent diferrocenyl–dihydrothiopyran derivatives | pl_PL |
dc.type | Article | pl_PL |
dc.page.number | 6268-6276 | pl_PL |
dc.contributor.authorAffiliation | Kowalski Konrad, Faculty of Chemistry, Department of Organic Chemistry, University of Łódź | pl_PL |
dc.contributor.authorAffiliation | Karpowicz Rafał, Faculty of Chemistry, Department of Organic Chemistry, University of Łódź | pl_PL |
dc.contributor.authorAffiliation | Mlostoń Grzegorz, Faculty of Chemistry, Department of Organic and Applied Chemistry, University of Łódź | pl_PL |
dc.contributor.authorAffiliation | Miesel Dominique, Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Department of Inorganic Chemistr | pl_PL |
dc.contributor.authorAffiliation | Hildebrandt Alexander, Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Department of Inorganic Chemistr | pl_PL |
dc.contributor.authorAffiliation | Lang Heinrich, Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Department of Inorganic Chemistr | pl_PL |
dc.contributor.authorAffiliation | Czerwieniec Rafał, Universität Regensburg, Institut für Physikalische und Theoretische Chemie, | pl_PL |
dc.contributor.authorAffiliation | Therrien Bruno, Institute of Chemistry, University of Neuchatel | pl_PL |
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dc.contributor.authorEmail | kondor15@wp.pl | pl_PL |
dc.identifier.doi | DOI: 10.1039/c5dt00246j | |
dc.relation.volume | 44 | pl_PL |